您的位置: 专家智库 > >

国家自然科学基金(51264010)

作品数:6 被引量:9H指数:2
相关作者:尹艳红羊建高吴子平黎业生曾辉更多>>
相关机构:江西理工大学东南大学中南大学更多>>
发文基金:国家自然科学基金中国博士后科学基金更多>>
相关领域:一般工业技术化学工程理学更多>>

文献类型

  • 6篇中文期刊文章

领域

  • 4篇一般工业技术
  • 3篇化学工程
  • 3篇理学

主题

  • 3篇英文
  • 3篇碳纳米管
  • 3篇纳米
  • 3篇纳米管
  • 2篇NANORO...
  • 2篇PREPAR...
  • 2篇WO
  • 2篇AS
  • 1篇性能研究
  • 1篇氧化钨
  • 1篇一步法
  • 1篇一步法制备
  • 1篇原位合成
  • 1篇碳化钨
  • 1篇球状
  • 1篇温度
  • 1篇高分散
  • 1篇PLATIN...
  • 1篇PT
  • 1篇SPHERE

机构

  • 3篇江西理工大学
  • 2篇东南大学
  • 2篇中南大学
  • 1篇教育部
  • 1篇纽约城市大学

作者

  • 2篇黎业生
  • 2篇吴子平
  • 2篇羊建高
  • 2篇尹艳红
  • 1篇刘咏
  • 1篇陈一胜
  • 1篇黄先亮
  • 1篇胡英燕
  • 1篇张伟波
  • 1篇曾辉
  • 1篇许前丰

传媒

  • 3篇稀有金属材料...
  • 2篇Rare M...
  • 1篇Journa...

年份

  • 1篇2022
  • 1篇2019
  • 1篇2016
  • 2篇2015
  • 1篇2014
6 条 记 录,以下是 1-6
排序方式:
Synthesis and Characterization of Sphere-like Pt Nanoparticles Supported on DWCNT/WO_3 Nanorods with Electrocatalytic Activity被引量:4
2015年
Tungsten oxide (WO3) nanorods, which were used to load platinum (Pt) nanoparticles, were investi- gated. H2WO4 nanorods with diameters from 10 to 50 nm were obtained when tungsten precursor was added into homogenous double-walled carbon nanotubes (DWCNT) and ethylene glycol (EG) solution. Nanosized rod-like WO3 were achieved after calcination of the DWCNT/H2W04 composite. Sphere-like Pt nanoparticles were loaded on the surface of the nanorods by EG in-situ reduction. Pt particles were isolated by DWCNT/WO3 nanorods and secondary accumulation could be prevented when Pt particles appeared in the DWCNT/WO3 nanorod/EG dispersion solution. Therefore, Pt nanoparticles with mean di- ameters of 2-6 nm could be obtained. Pt-deposited on DWCNT/WO3 nanorods exhibited high electrochemical activity, which could facilitate the low-cost mass production of Pt catalyst.
Yanhong YinChun'an MaZiping WuMan ZhaoLitao ChenYouqun Chu
气氛和温度对一步法制备碳化钨的影响(英文)被引量:4
2014年
介绍了一种一步法制备碳化钨(WC)的新方法,以钨酸钠为原料,通过碳纳米管模板和载体制备小颗粒钨酸,制备出钨酸和碳黑的混合物作为反应前驱体,分别以H2和N2作为还原及保护气体合成WC,当合成温度高于800℃,反应前反应管内抽成真空,并在反应管内通入氢气和氮气流时,WO3首先被还原为W,接下来W被还原为W2C,最后,W2C被还原为最终产物WC。实验过程中通过调节气氛和温度2个重要反应条件,探索出了控制WC形貌及大量制备的方法,为WC的低成本及可控制备提供了新的途径。
吴子平黄先亮尹艳红胡英燕黎业生羊建高曾辉
关键词:碳化钨碳纳米管温度
高分散、超细Pt颗粒在碳纳米管上的制备及其作为高效电催剂性能研究(英文)被引量:1
2015年
研究了不同分散程度的双壁碳纳米管(DWCNTs)作为载体沉积Pt,得到了尺寸2.08 nm的Pt颗粒均匀分散于DWCNTs表面。这种尺寸与分散状态的Pt颗粒相比其样品显示了极高的电催化活性(电流密度为0.022 A·cm-2,电化学比表面积为86.38 m2·g-1)。进一步的分析表明,载体在溶液中的浓度对形成Pt颗粒的尺寸和分布具有重要影响,这种尺寸与分散状态的Pt颗粒可以实现高电催化活性和低成本的Pt催化剂制备。
吴子平张伟波尹艳红黎业生陈一胜羊建高刘咏许前丰
关键词:碳纳米管高分散超细
以锯齿状碳纳米管为模板原位合成微/纳米球状氧化钨(英文)被引量:1
2019年
以锯齿状CNTs管束作为模板担载H_2WO_4前驱体。在液相沉积过程中H_2WO_4被锯齿状CNTs包裹,所得H_2WO_4/CNTs团簇的平均尺寸为500 nm,由直径10~20 nm的H_2WO_4组成,比表面积和孔容分别为85.24 m^2·g^(-1)和0.2933 m^3·g^(-1)。将H_2WO_4/CNTs置于氧气气氛中进行热处理,除去CNTs后,得到了由纳米颗粒组成的WO_3微米球,比表面积和孔容分别为18.7 m^2·g^(-1)和0.2055 m^3·g^(-1)。结果表明,锯齿状CNTs对有效调节分层结构WO_3发挥重要作用,对制备微纳米结构材料具有广阔的应用前景。
尹艳红童珍幸康虔吴子平黎业生刘先斌梁同祥廖春发蒋隆科邵健锋
关键词:球状氧化钨
Preparation of WO_(3) nanorods with high specific surface area using double-walled carbon nanotubes as template被引量:1
2022年
The preparation of WO_(3) nanorods by double-walled carbon nanotube(DWCNT)template was investi-gated in this study.Owing to that the prepared H_(2)WO_(4)can be isolated by the homogenously dispersed DWCNT bun-dles and secondary accumulation can be avoided effec-tively,the growth of H_(2)WO_(4) can be restrained,and H_(2)WO_(4) nanorods with diameter of 10–50 nm can be prepared.After calcination of the prepared DWCNT/H_(2)WO_(4) com-posite in oxygen,WO_(3) nanorods with diameter of 10–100 nm and high specific surface area of 16.4 m^(2)·g^(-1) can be obtained.It is concluded that the DWCNTs play an im-portant role in the effective mediation of the morphology and size of nano-WO_(3).
Yan-Hong YinChun-An MaZi-Ping WuLi-Tao ChenYou-Qun Chu
关键词:NANORODSTEMPLATE
Preparation of homogeneously dispersed and highly concentrated double-walled carbon nanotubes as catalyst support
2016年
In this study, double-walled carbon nanotubes (DWCNTs) in ethylene glycol (EG) and N,N-dimethyl- formamide (DMF) media were investigated by a simple ultrasonication method. Homogeneously dispersed and highly concentrated DWCNTs are in EG (95 vol%) and DMF (5 vol%) media without the addition of surfactant. Surface structure and crystallinity of DWCNTs undergo minimal change. The highly concentrated dispersion state of DWCNTs helps in Pt loading. Pt particles prepared in the homogenous dispersion system have small sizes and are uniformly distributed. The prepared Pt catalysts display a similar electrochemical activity to catalysts pre- pared in EG system with low concentration. The results demonstrate that homogenously dispersed and highly concentrated DWCNTs can realize mass production of Pt/ DWCNT catalysts with high electrochemical activity and low cost.
Ming-Mao LiZi-Ping WuMan ZhaoWei-Bo ZhangYing-Yan HuYan-Hong Yin
共1页<1>
聚类工具0