The electrochemical performance of Ta-doped Li4Ti5O12 in the form of Li4Ti4.95Ta0.05O12 was characterized.X-ray diffraction(XRD) and scanning electron microscopy(SEM) were employed to characterize the structure and morphology of Li4Ti4.95Ta0.05O12.Ta-doping does not change the phase composition and particle morphology,while improves remarkably its cycling stability at high charge/discharge rate.Li4Ti4.95Ta0.05O12 exhibits an excellent rate capability with a reversible capacity of 116.1 mA·h/g at 10C and even 91.0 mA·h/g at 30C.The substitution of Ta for Ti site can enhance the electronic conductivity of Li4Ti5O12 via the generation of mixing Ti4+/Ti3+,which indicates that Li4Ti4.95Ta0.05O12 is a promising candidate material for anodes in lithium-ion battery application.