Effect of mischmetal addition on the cast microstructure of 6063 alloys has been investigated by means of optical microscopy, TEM and anode filming etc. The results show that there is a critical content of fining dendrite structure by adding mischmetal to 6063 alloys. This critical mischmetal content is about 0.15%. Only when the mischmetal content is above 0.15%, the secondary dendrite arm spacing decreased and eutectic structure fined. The cast grain is obviously refined when the content of mischmetal is lower. Consideration from the cast structure, the suitable mischmetal content in 6063 alloys is 0.20%.