For environment protection and high efficiency, development of new conceptpower plant has been required in China. The fuel cell is expected to be used in a power plant as acentralized power Station or distributed power plant. It is a chemical power generation device thatconverts the energy of a chemical reaction directly into electrical energy and not limited by Carnotcycle efficiency. The molten carbonate fuel cell (MCFC) power plant has several attractive featuresi.e. high efficiency and lower emission of NO_x and SO_x A combined cycle generation system withMCFC and steam turbine is designed. Its net electrical efficiency LHV is about 55 percent.