A new coordination complex [Cu((DETA)]3[Cr(CN)6]2·5H2O (DETA=diethylenetriamine) was synthesized, its crystal structure and magnetic properties were determined. The crystal crystallizes in monoclinic space group P21/c, with unit cell constants a=2.056 6(7) nm, b=1.440 7(5) nm, c=1.513 3(5) nm, β=95.996(6)°, and V=4.459(3) nm3, Z=4, Dc=1.499 g·cm-3, F(000)=2 060, μ(Mo Kα)=1.936 mm-1, R1=0.052 3, wR2=0.106 2. The structure consists of a one-dimensional chain of [Cu(DETA)]2[Cr(CN)6]+ and binuclear [Cu(DETA)][Cr(CN)6]-. The coordination geometries around Cu2+ atoms are distorted square-based pyramidal and distorted square, respectively. Magnetism studies show that there are ferromagnetic interactions between Cu2+ and Cr3+ ions. CCDC: 272213.
The cyano-bridged bimetallic complex [Nd(DMSO)2(H2O)2][Ni(CN)4]Cl with two-dimensional gridding molecule structure was synthesized and characterized. In the complex all four cyano groups of unit Ni(CN)42- are bound to Nd3+ ions. The crystal data for the title complex: monoclinic, space group P21/c, a=0.780 0(3) nm, b=1.509 7(6) nm, c=1.683 2(6) nm, β=115.231(14)°, Z=4, μ=4.311 mm-1, final R1=0.020 9, wR2=0.045 4. CCDC: 272214.
The title complex [La(DMSO)3(H2O)3Cr(CN)6]H2O was obtained by the reaction of LaCl37H2O, DMSO and K3[Cr(CN)6] in aqueous solution on a hot water bath. The crystal crystallizes in orthorhombic, space group P212121 with a = 9.827(3), b = 15.037(4), c = 17.633(5) ? C12H26CrLaN6O7S3, Mr = 653.48, Z = 4, V = 2605.7(13) ?, Dc = 1.666 g/m3, (MoKa) = 2.314 mm-1, F(000) = 1300, R = 0.0205 and wR = 0.0481 for 5038 observed reflec- tions (I > 2s(I)). La3+ ion is eight-coordinated by three DMSO molecules, three H2O molecules and two [Cr(CN)6]3- units. The structure of the title complex possesses a cyano-bridged one- dimensional zigzag chain structure with alternating La(DMSO)3(H2O)3 and Cr(CN)6 moieties, which are linked by some hydrogen bonds to form a 3D network structure.
The cyano-bridged bimetallic complex K3(TMS)2(H2O)2Cr(CN)6 with three- dimensional microporous structure was synthesized and characterized. The title complex (C14H20CrK3N, Mr = 601.78) crystallizes in monoclinic, space group C2/c with a = 14.357(4), b = 9.331(3), c = 19.180(6) ?, β = 96.754(5)o, V = 2551.6(13) ?3, Z = 4, Dc = 1.567 g/m3, μ(MoKα) = 1.141 mm-1, F(000) = 1228, the final R = 0.0440 and wR = 0.0990 for 1760 observed reflections (I > 2σ(I)). In the crystal, two [Cr(CN) ]3- units, four K+ ions and two oxygen atoms of two 6 TMS molecules are linked to form a sixteen-membered ring and an extended three-dimensional structure.
A new cyano-bridged complex Eu(DMSO)3(H2O)3Cr(CN)6·H2O with one-dimensional chain molecular structure was synthesized and characterized. The crystal data for the title complex: orthorhombic, P212121, a=0.972 2(3) nm, b=1.489 5(4) nm, c=1.748 6(5)nm, Z=4, μ=3.171 mm-1, final R1=0.020 4, wR2=0.043 4. From magnetic susceptibility measurements the complex was found to exhibit a weak ferromagnetic interaction between the Eu (III) and Cr(III) atoms. CCDC: 272212.
A novel title complex, C23H19N2O19Na4Y （Mr= 808.27）, has been synthesized by hydrothermal reaction and structurally characterized by X-ray diffraction. It crystallizes in monoclinic, space group P21/n with a = 13.560（3）, b = 14.016（3）, c = 14.948（4） A, β = 99.492（4）°, Z = 4, V = 2802.2（12） A^3, Dc = 1.916 g/cm^3,μ（MoKα） = 2.241 mm^-1, F（000） = 1624, the final R = 0.0337 and wR = 0.0828 for 4044 observed reflections（I〉 2σ（I））. In the crystal, each eight- coordinated Y（Ⅲ） atom is linked by carboxyl groups of BTC to form a one-dimensional helical network structure.
A novel coordination polymer nickel 1,3,5-benzenetricarboxylate (TMA) Ni3(H2O)6(TMA)3-(TMA)23-·2H2O with two-dimensional porous structure was synthesized and characterized. It crystallizes in the hexagonal system, space group P6522, with a=1.665 2(10) nm, c=2.045 4(11) nm, V=4.912(5) nm3, Z=6, Dc=1.916 g·cm-3, μ(Mo K)=0.181 8 mm-1, F(000)=2 892. The final R1=0.066 4, wR2=0.175 6 for 2 710 observed reflections [I>2σ(I)] out of 2 904 unique reflections . This coordination polymer reveals not only two-dimensional porous structure but also particular magnetic properties. CCDC: 274177.
The title complex [La(betaine)2(H2O)6Fe(CN)6]?2H2O (betaine = (CH3)3NCH2CO2) has been synthesized and characterized by X-ray single-crystal structure analysis. The crystal crystallizes in monoclinic, space group P21/n with a = 15.793(5), b = 8.927(3), c = 22.257(7) ?, β = 110.147(5)o, C16H38FeLaN8O12, Mr = 729.31, Z = 4, V = 2946.0(15) ?3, Dc = 1.640 g/m3, μ(MoKα) = 1.988 mm-1, F(000) =1476, R = 0.0388 and wR = 0.0827 for 4237 observed reflections (I > 2σ(I)). The La3+ ion is nine-coordinated by one cyano nitrogen atom and eight oxygen atoms of two betaine and six water molecules. Each complex molecule is connected to form a 3D network structure by some O–H…O and O–H…N hydrogen bonds.
