Collision and security issues are considered as barriers to RFID applications.In this paper,a parallelizable anti-collision based on chaotic sequence combined dynamic frame slotted aloha to build a high-efficiency RFID system is proposed.In the tags parallelizable identification,we design a Discrete Markov process to analyze the success identification rate.Then a mutual authentication security protocol merging chaotic anti-collision is presented.The theoretical analysis and simulation results show that the proposed identification scheme has less than 45.1%of the identification time slots compared with the OVSF-system when the length of the chaos sequence is 31.The success identification rate of the proposed chaotic anti-collision can achieve 63%when the number of the tag is100.We test the energy consumption of the presented authentication protocol,which can simultaneously solve the anti-collision and security of the UHF RFID system.