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Creation of surface defects on carbon nanofibers by steam treatment被引量：1: 2013年; A direct strategy for the creation of defects on carbon nanofibers (CNFs) has been developed by steam treatment.Nitrogen physisorption,XRD,Raman spectra,SEM and TEM analyses proved the existence of the new defects on CNFs.BET surface area of CNFs after steam treatment was enhanced from 20 to 378 m2/g.Pd catalysts supported on CNFs were also prepared by colloidal deposition method.The different activity of Pd/CNFs catalysts in the partial hydrogenation of phenylacetylene further demonstrated the diverse surfaces of CNFs could be formed by steam treatment.; Zhengfeng ShaoMin PangWei XiaMartin MuhlerChanghai Liang; 关键词：PALLADIUM

Two-step hydrogenolysis of biomass-derived glucose to polyols over CuCr catalysts: ＜正＞Introduction With the declining of fossil feedstocks and theincreasing requirements,and the political and e...; Z.H.XiaoS.H.JinC.H.Liang; 关键词：HYDROGENOLYSIS GLUCOSE POLYOLS; 文献传递

Hydrodeoxygenation of lignin-derived methoxyl-rich compounds over supported nickel catalysts: ＜正＞Introduction Lignin, as the abundant and renewable resources inthe nature, makes up 20-30 wt% of lignocellu...; S.JinZ.XiaoJ.XingC.Liang; 关键词：LIGNIN HYDRODEOXYGENATION; 文献传递

纳米Pd的形貌和尺寸可控制备及其1,4-丁炔二醇加氢性能被引量：5: 2013年; 采用化学还原法合成Pd纳米立方体,并将其作为晶种,进一步合成大尺寸的纳米Pd立方体以及具有不同{100}和{111}晶面比例的纳米Pd多面体.将形貌和尺寸可控的纳米Pd溶胶应用于1,4-丁炔二醇催化加氢的反应中,反应结果表明,纳米Pd的催化性能取决于其尺寸和形貌.{111}晶面的催化活性高于{100}晶面,PVP稳定的Pd胶体对1,4-丁烯二醇均具有较高选择性,具有适当{100}和{111}晶面比例的纳米Pd多面体对1,4-丁烯二醇的选择性可达96%.; 刘倩李闯陈霄梁长海; 关键词：晶种法 1,4-丁炔二醇选择加氢

An eco-friendly paradigm for the synthesis of sorbitan and isosorbide through dehydration of sorbitol catalyzed by bio-based and decomposable formic acid: ＜正＞Introduction Depletion of fossil resources and environmental degradation due to huge emission of harmful ga...; Min PangZihui XiaoXiaoling GuoChanghai Liang; 关键词：SORBITOL ISOSORBIDE DEHYDRATION; 文献传递

纳米银制备的最新科研成果转化为本科生实验的探索与实践被引量：10: 2011年; 将纳米银制备的最新科研成果转化为本科生实验,让学生在本科阶段能初步体会到科研的基本思路和方法。该实验引入到本科教学环节中,一方面可以弥补很多高校缺少界面反应实验的不足,另一方面,本实验操作简单,现象非常明显,又具有一定的科研思想,对本科生的科研思维的培养有很好的作用。; 方实耿王新葵谭小英; 关键词：纳米银相转移法创新性实验

用于Suzuki-Miyaura反应的阴离子交换树脂负载钯催化剂(英文)被引量：3: 2013年; 以碱性阴离子交换树脂Amberlite IRA-900为载体,Pd(C3H5)(C5H5)为金属有机前体,采用金属有机气相沉积法在室温下制备了Pd@IRA-900多相催化材料.紫外-可见光谱分析证明前体和树脂骨架之间的化学作用以及树脂本身的孔道结构使得Pd纳米粒子均匀分散在载体上.透射电镜结果显示钯纳米粒子的平均尺寸为2.6 nm.在较温和的条件下Pd@IRA-900对多种卤代芳烃和苯硼酸的Suzuki偶联都具有良好的催化活性,并且催化剂重复使用5次之后依然具有很好的活性.此外,对树脂载体进行碱性交换处理后可得到一种双功能催化材料Pd@IRA-900(OH),该催化剂在不加入碱的条件下也可以催化碘苯和苯硼酸的Suzuki偶联反应.; 张明明江曼曼梁长海; 关键词：钯阴离子交换树脂 SUZUKI偶联双功能催化剂

Hydrogenation of succinic acid to γ-butyrolactone and tetrahydrofuran on Pd-Re/C catalysts: ＜正＞Introduction With the decline of available fossil fuels and response to environmental needs, demand for fin...; Zhengfeng ShaoChuang LiXin DiZihui XiaoChanghai Liang; 关键词：HYDROGENATION Γ-BUTYROLACTONE TETRAHYDROFURAN; 文献传递

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国家自然科学基金(20906008)