The ESR signal of lithium intercalated MCMB can be well simulated by combination of a Lorentz curve and a Gauss curve. The ESR intensity of the Lorentz component is essentially independent of temperature while the Gauss component shows a linear change with the reciprocal of temperature, indicative of Pauli spin and Curie spin, respectively. The former is probably associated with the ordered (graphitized) structures while the latter with the disordered structures in the sample.