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国家自然科学基金(20725620)

作品数:3 被引量:25H指数:3
相关作者:陈燕陈玉赵亮高金森更多>>
相关机构:中国石油大学(北京)更多>>
发文基金:国家自然科学基金国家教育部博士点基金更多>>
相关领域:化学工程石油与天然气工程理学更多>>

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Experimental and computational studies on flow behavior of gas-solid fluidized bed with disparately sized binary particles被引量:8
2008年
This paper presents experimental and computational studies on the flow behavior of a gas-solid fluidized bed with disparately sized binary particle mixtures. The mixing/segregation behavior and segregation efficiency of the small and large particles are investigated experimentally. Particle composition and operating conditions that influence the fluidization behavior of mixing/segregation are examined. Based on the granular kinetics theory, a multi-fluid CFD model has been developed and verified against the experimental results. The simulation results are in reasonable agreement with experimental data. The results showed that the smaller particles are found near the bed surface while the larger particles tend to settle down to the bed bottom in turbulent fluidized bed. However, complete segregation of the binary particles does not occur in the gas velocity range of 0.695-0.904 m/s. Segregation efficiency increases with increasing gas velocity and mean residence time of the binary particles, but decreases with increasing the small particle concentration. The calculated results also show that the small particles move downward in the wall region and upward in the core. Due to the effect of large particles on the movement of small particles, the small particles present a more turbulent velocity profile in the dense phase than that in the dilute phase.
Jinsen Gao Jian Chang Chunxi Lu Chunming Xu
关键词:MIXINGSEGREGATION
噻吩在Ni(100),Cu(100),Co(100)表面吸附的密度泛函研究被引量:6
2010年
采用密度泛函理论对噻吩分子在Ni(100),Cu(100)和Co(100)表面的吸附构型进行了GGA/PBE水平上的计算,通过比较吸附能及各结构参数,预测了各金属的脱硫活性.结果表明:噻吩在Ni表面发生了作用力较强的化学吸附,噻吩的S—C键有解离趋势;在Cu表面发生的是作用力较弱的物理吸附,噻吩分子构型并未发生较大变化;而噻吩在Co表面的吸附作用最强,噻吩的S—C键已经发生解离,和Co原子之间的距离已经达到甚至短于Co—S键的键长.这说明,金属的吸附脱硫活性为Co>Ni>Cu,与实验研究结果一致.此3种金属最稳定的分子吸附位均为hol45位.
赵亮陈燕高金森陈玉
关键词:噻吩脱硫密度泛函理论
Drag models for simulating gas–solid flow in the turbulent fluidization of FCC particles被引量:13
2009年
This paper examines the suitability of various drag models for predicting the hydrodynamics of the turbulent fluidization of FCC particles on the Fluent V6.2 platform. The drag models included those of Syamlal-O'Brien, Gidaspow, modified Syamlal-O'Brien, and McKeen. Comparison between experimental data and simulated results showed that the Syamlal-O'Brien, Gidaspow, and modified Syamlal-O'Brien drag models highly overestimated gas-solid momentum exchange and could not predict the formation of dense phase in the fiuidized bed, while the McKeen drag model could not capture the dilute charac- teristics due to underestimation of drag force. The standard Gidaspow drag model was then modified by adopting the effective particle cluster diameter to account for particle clusters, which was, however, proved inapplicable for FCC particle turbulent fluidization. A four-zone drag model (dense phase, sub- dense phase, sub-dilute phase and dilute phase) was finally proposed to calculate the gas-solid exchange coefficient in the turbulent fluidization of FCC particles, and was validated by satisfactory agreement between prediction and experiment.
Peng Li Xingying Lan Chunming Xu Gang Wang Chunxi Lu Jinsen Gao
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