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国家自然科学基金(s50938004)

作品数:3 被引量:37H指数:3
相关作者:张雅玲孙成李文超陈泓哲杨绍贵更多>>
相关机构:南京大学更多>>
发文基金:国家自然科学基金江苏省环境监测科研基金更多>>
相关领域:化学工程理学轻工技术与工程农业科学更多>>

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新型固相微萃取-高效液相色谱测定牛奶中4种磺胺类药物残留被引量:26
2013年
采用原位聚合法在经修饰的不锈钢丝表面键合聚(甲基丙烯酸-乙二醇二甲基丙烯酸酯)材料,并以之作为固相微萃取纤维涂层,调节样品基质至pH 5,在30℃萃取50 min,在乙腈和0.1%甲酸(20∶80,V/V)中解吸12 min,同时与高效液相色谱联用,建立了牛奶中4种典型磺胺类药物残留的分析方法。实验结果表明,本方法的日内(n=3)和日间(n=5)精密度(RSD)分别小于6.1%和2.8%,平均加标回收率在68.2%~100.3%之间;涂层的制备重现性和实验重现性较好(RSD<5.82%,n=4),4种磺胺类化合物的线性范围为10~500μg/L,线性相关系数r>0.99,检出限在2~10μg/L之间。
彭英何欢孙成张雅玲李文超陈泓哲杨绍贵
关键词:固相微萃取高效液相色谱磺胺类药物牛奶
Selective removal of nitrate by using a novel macroporous acrylic anion exchange resin被引量:5
2012年
An anion exchange resin NDP-5 has been prepared successfully and applied on the selective removal of nitrate from SO_4^(2-)/ NO_3^- binary co-existence system.The composition and morphology of NDP-5 were confirmed by FT-IR and SEM.The NDP-5 resin exhibits the completely different behavior on the adsorption capacity,adsorption kinetic and the effect of the completing anion in the absence or presence of sulfate,compared to D213.And,the resultants of kinetic are well fitted by the pseudo-first-order and pseudo-second-order models.These results are very important to develop novel resins with great features.
Hai Ou SongYang ZhouAi Min LiSandra Mueller
关键词:NITRATEADSORPTION
Preparation of a novel magnetic powder resin for the rapid removal of tetracycline in the aquatic environment被引量:6
2012年
Magnetic powder resin Q150 with high specific surface area of 1074 m2/g was prepared by the membrane emulsificationsuspension polymerization technique. Adsoption of tetracycline on the obtained sorbent Q150 was evaluted by using the granule resin (GR) XAD-4, the powder activated carbon (PAC) 1240AC and the granule activated carbon (GAC) HD4000 for comparison. It was found that Q150 had a larger adsorption capacity, faster kinetic and easier regeneration under alkaline condition. The results suggested that the powder resin (PR) Q150 would be a promising sorbent for removing antibiotics and even other organic micropollutants from the aquatic environment.
Qing ZhouI Man Cheng Zhang Chen Dong Shuang Zhe Qin Li Ai Min Li
关键词:MICROPOLLUTANTANTIBIOTICSADSORPTION
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