A new one-dimensional（1D） coordination polymer [Zn（MMTA）2]n（MMTA=5-mercapto-l-methyl-tetrazole） was synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction. This compound crystallizes in the monoclinic space group C2/c, with cell parameters： a=1.4938（7） nm, b=1.3599（5） nm, c=1.2180（4） nm, fl=120.84（3）^＊, V=2.1243（2） nm^3, and Z=8. The deprotonated HMMTA molecule as a/a2-1igand links the zinc center, forming ID chains, which are luther linked by weak C--H...N hydrogen bonds, forming a three-dimensional supramolecular framework. The compound exhibits intense photoluminescence at room temperature. On the basis of the results of TG/DTA analyses, the structure is thermally stable up to -280 ℃.
WANG LeiZHANG HuiDONG Wen-junSHI ZhanFENG Shou-hua
With dimethylamine as a template, a new one-dimensional zincophosphite （C2H8N）·[Zn（HPO3）（H2PO3）] was prepared under hydrothermal conditions and characterized by single-crystal X-ray diffraction, FTIR spectrametry, elemental analysis, powder X-ray diffraction, and thermogravimetric analysis. The compound crystallized in the Monoclinic space group P2（1）/c, with cell parameters, a=0.78410（9） nm, b=1.54744（2） nm, c=0.81418（1） nm, β=105.8150（1）°, V=0.95049（2） nm3 and Z=4. The connectivity of the ZnO4 tetrahedron and HPO3 pseudo pyramid resulted in inifinite corner-sharing 4-membered ring chains, which were further linked by the protonated amine molecules to form a 3D structure via hydrogen bonds. To the best of our knowledge, this is the first existence of a zincophosphite with the anionic framework composition of [Zn（HPO3）（H2PO3）]-. The compound exhibits intense photoluminescence at room temperature.
WANG LeiLUO Yan-lingWEN Yong-hongLI Guang-huaFENG Shou-hua
