To analyze the magnetic properties of Nd_(2)Fe_(14)B compound under high pressure,an improved two-sublattice molecular field model coupled with equivalent stress field was applied to study the effect of pressure on magnetization,magnetostriction coefficient,susceptibility and Curie temperature.The calculation results show that the pressure has a stronger effect on the magnetization of Fe sublattice compared to that of Nd sublattice at varied temperatures when the external magnetic field is parallel to the alignment direction.Saturated magnetization,initial susceptibility and magnetic moment of Nd_(2)Fe_(14)B compound are found to decrease gradually with pressure increasing,and the Curie temperature of Nd_(2)Fe_(14)B decreases to about 298 K under an applied pressure of 1.15 GPa.The results suggest that the pressure-induced magnetic phase transition of Nd2Fe14B occurs under 1.15 GPa at room temperature.
为了研究钕铁硼铁磁性材料在冲击波作用下的力学与磁学性质,利用一级轻气炮驱动飞片的方法对钕铁硼进行冲击加载实验,采用锰铜压阻传感器测量了钕铁硼内部不同位置的压力变化历程。给出了3~7 GPa压力范围内,钕铁硼的Hugoniot关系以及冲击波阵面上压力与温度的关系;计算了钕铁硼的Grüneisen状态方程参数;建立了飞片碰撞加载钕铁硼的计算模型,对钕铁硼的冲击响应进行了数值模拟计算,计算得到的压力峰值与实验测得的压力峰值基本相符。对冲击后的磁体进行了微观结构观测,分析了钕铁硼退磁机制。结果发现:冲击后磁体发生沿晶断裂,磁体晶界相的微观结构没有发生变化,沿晶断裂弱化了晶界相隔断主相之间交换耦合的作用。经冲击的磁体的矫顽力损失很大,从21.4 k Oe降至3.2 k Oe,在难磁化方向矫顽力只有1.2 k Oe,但难易磁化方向并未发生改变。