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国家自然科学基金(51278051)

作品数:3 被引量:13H指数:1
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腐殖酸与镉离子在水合二氧化锰表面的分配系数研究被引量:1
2015年
水体中腐殖酸(HA)和金属离子广泛存在,二者的相互作用对其在水中天然矿物颗粒表面的吸附、降解等环境行为具有重要影响.本文采用离子交换平衡法测定了HA和镉离子(Cd(Ⅱ))的配位数(co-ordination number,x)和络合稳定常数(complex stability constant,K),系统考察了pH值和离子强度对x和K的影响,并研究了HA和Cd(Ⅱ)在水合二氧化锰(HMO)表面的分配关系.结果表明:pH值对HA和Cd(Ⅱ)的配位数影响较小(x=1.651~1.752),而对络合稳定常数影响显著(log K=1.652~3.548);在不同pH值条件下,离子强度对HA和Cd(Ⅱ)的络合稳定常数影响均较小,而其配位数均随溶液离子强度的增加而提高;不同温度条件下,HA-Cd(Ⅱ)络合物在HMO表面的分配系数(Kd)均低于HA和Cd(Ⅱ)在HMO表面的分配系数,表明HA-Cd(Ⅱ)络合体系的存在抑制了HMO对Cd(Ⅱ)和HA的去除作用.
翟羽佳王建铎王思达王洪杰
关键词:腐殖酸水合二氧化锰配位数
CH_4 emission and conversion from A^2O and SBR processes in full-scale wastewater treatment plants被引量:12
2014年
Wastewater treatment systems are important anthropogenic sources of CH4 emission. A full-scale experiment was carried out to monitor the CH4 emission from anoxic/anaerobic/oxic process (A2O) and sequencing batch reactor (SBR) wastewater treatment plants (WWTPs) for one year from May 2011 to April 2012. The main emission unit of the A2O process was an oxic tank, accounting for 76.2% of CH4 emissions; the main emission unit of the SBR process was the feeding and aeration phase, accounting for 99.5% of CH4 emissions. CH4 can be produced in the anaerobic condition, such as in the primary settling tank and anaerobic tank of the A2O process. While CH4 can be consumed in anoxic denitrification or the aeration condition, such as in the anoxic tank and oxic tank of the A2O process and the feeding and aeration phase of the SBR process. The CH4 emission flux and the dissolved CH4 concentration rapidly decreased in the oxic tank of the A2O process. These metrics increased during the first half of the phase and then decreased during the latter half of the phase in the feeding and aeration phase of the SBR process. The CH4 oxidation rate ranged from 32.47% to 89.52% (mean: 67.96%) in the A2O process and from 12.65% to 88.31% (mean: 47.62%) in the SBR process. The mean CH4 emission factors were 0.182 g/ton of wastewater and 24.75 g CH4/(person.year) for the A2O process, and 0.457 g/ton of wastewater and 36.55 g CH4/(person.year) for the SBR process.
Yan LiuXiang ChengXiaoxiu LunDezhi Sun
Long-range transport of organic aerosol to Cape Hedo,Japan
2014年
An investigation at Cape Hedo, Japan, from 2005 to 2006, focused on the long-range transport of organic aerosol (OA) from the Asian continent. An Aerodyne aerosol mass spectrometer was used to investigate the OA data collected over the study. OA concentrations were low from July to September and peaked during March and April. Based on air mass origins, four OA source regions were identified: northern China, southern China, Japan, and Korea. OA concentrations measured at Cape Hedo from the four sources did not exhibit large differences. Conversely, the frequencies of the air masses reaching Cape Hedo from the different regions varied considerably. Northern China was identified as the primary source of organic aerosols at Cape Hedo. Examination of variations in the ratio of m/z 44 to OA concentrations with transport time showed that OAs were partially oxidized during transport
Xiaoxiu LunAkinori TakamiWeifang MaAkio ShimonoShiro Hatakeyama
北京地区小麦-玉米轮作田CO_2、N_2O和CH_4季节排放特征
<正>大气中C02、CH4和N20是重要的温室气体,它们对全球气候变暖的增温贡献分别是60%,15%和5%[l]。由于人类活动的影响,大气中C02、CH4和N20的浓度以每年0.5%,1.1%和0.3%的速度增加[l]。...
李晓密伦小秀
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