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国家自然科学基金(10904097)

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Crystal growth,structural and physical properties of the 5d noncentrosymmetric LaOsSi_3
2013年
LaOsSi3 single crystals are synthesized for the first time by an arc melting method. The crystal features a tetrag- onal BaNiSn3-type structure (space group 14mm) which lacks inversion symmetry along the crystallographic c axis and is isostructural with the intensively studied Rashba-type noncentrosymmetric superconductors LaRhSi3 and LaIrSi3. Un- like LaRhSi3 and LaIrSi3 displaying superconductivity, LaOsSi3 shows only metallic behavior over the measured temper- ature range of 2 K-300 K. The Sommerfeld coefficient ]/derived from specific heat is 5.76 mJ.mol-1 -K-2, indicating that LaOsSi3 has a weak electronic correlation effect. The absence of superconductivity in LaOsSi3 may lie in the Os 5d bands in the electronic structure. If it is true, it would be useful to provide complementary knowledge in understanding the relation between conduction and the d bands of M in LaMSi3 compounds (M = transition metals).
张旭苗杉杉王瀑郑萍尹文龙姚吉勇姜宏伟王海石友国
阳极氧化铝模板表面自组装四方网格的形成研究
以草酸为电解液,分别用一次氧化和二次氧化制备了阳极氧化铝模板,二次氧化得到了大范围的大小均一,排列有序的纳米孔阵列。用原子力显微镜(AFM)和扫描电镜(SEM)观测了形成的模板。对一次氧化形成的氧化膜观察发现在大范围三角...
甄营王海姜宏伟
关键词:氧化铝模板自组织机制亚稳态
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