By means of a stochastic model suggested in this paper for the systems with local non-equilibrium excited thermal fluctuations, the famous Shannon entropy is extended to include the heat conduction processes controlled externally by boundary constraints of constant temperature gradients at two sides.Meanwhile,using the description of master equation for the continuous Markov processes a balance equation of stochastic entropy production valid for one dimension gaseous heat conduction systems with high values of Prandtl number has been also established.Based on it,a general expression for both the stochastic entropy production and the entropy production of fluctuations have been further deduced by theΩ-expansions.In this formalism,all kinds of stochastic contributions to the dissipation from the non-equilibrium thermal fluctuation and internal noise turn explicit.
A two-dimensional generalized Langevin equation is proposed to describe the protein conformational change, compatible to the electron transfer process governed by atomic packing density model. We assume a fractional Gaussian noise and a white noise through bond and through space coordinates respectively, and introduce the coupling effect coming from both fluctuations and equilibrium variances. The general expressions for autocorrelation functions of distance fluctuation and fluorescence lifetime variation are derived, based on which the exact conformational change dynamics can be evaluated with the aid of numerical Laplace inversion technique. We explicitly elaborate the short time and long time approximations. The relationship between the two-diraensional description and the one-dimensional theory is also discussed.
